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REDOX Equation balancing + solving?


abelkoontz

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I-(aq) + HSO4-(aq) -> I2(aq) + SO2(g) 

How do you solve this? 

I just learned this, but if they are both - charge on the left, how can one be oxidized and the other reduced if they are both 0 oxidation states on the right? WHAT AM I MISSING? They should be 0 on both sides right.. can someone solve this and explain it? I don't really get it. tHANKS 

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2I- + HSO4- + 3H+--> I2 + SO2 + 2H2O (Acidic condition balance) Now if we add 3 hydroxides to both sides
2I- + HSO4- + H2O --> I2 + SO2 + 3OH-

The key is thus to first balance oxidation states, then balance oxygens, then balance H+ to get acid conditions, and if question asks, add equal number of hydroxides to both sides and find basic conditions. 

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