Lynn Gweeny Posted October 19, 2017 Report Share Posted October 19, 2017 Hello, could somebody explain the attached problems? Also, for Q13, how can you infer the polarity with a rough idea of electronegativity? Do you need to know the values for some elements? Thanks in advance! Reply Link to post Share on other sites More sharing options...
kw0573 Posted October 23, 2017 Report Share Posted October 23, 2017 Without databooklets you just have to know 13. Rememeber that alkanes are non polar, but ketones, haloalkanes, and amines are all polar. 13. B Electrophilic substitution adds something to the aromatic ring carbon, not on a substituent. 36. C A lot of enantiomers contain a carbon bonded to 4 different groups. In 37. B, the third carbon from the left is bonded to an ethyl group, hydrogen, bromine, and a methyl group. 1 Reply Link to post Share on other sites More sharing options...
IB_taking_over Posted October 23, 2017 Report Share Posted October 23, 2017 13. The answer is C-H in the CH4 a. C=O : 3.4-2.6= .8 || b. C-H : 2.6-2.2= .4 || c. C-Cl : 3.2-2.6= .6 || d. N-H : 3.0-2.2= .8 (For reference; I am aware you don't get these values on Paper 1) You can deduce based on the trend that C-H will be less polar than N-H and that C=O will be more polar than C-Cl. So, now we are down to C-H and C-Cl. We know that Cl has a relatively high electronegativity as it's on the far right. Which means that C-Cl has more polarity. (For the most part, if one of the options has a N, O, F, or Cl they are going to be the most polar option.) So, C-H is the answer. 1 Reply Link to post Share on other sites More sharing options...
Lynn Gweeny Posted October 23, 2017 Author Report Share Posted October 23, 2017 4 hours ago, kw0573 said: Without databooklets you just have to know 13. Rememeber that alkanes are non polar, but ketones, haloalkanes, and amines are all polar. 13. B Electrophilic substitution adds something to the aromatic ring carbon, not on a substituent. 36. C A lot of enantiomers contain a carbon bonded to 4 different groups. In 37. B, the third carbon from the left is bonded to an ethyl group, hydrogen, bromine, and a methyl group. Ohhh thank you! Reply Link to post Share on other sites More sharing options...
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